神马作文网Bidentate chiral phosphine ligands have received increasing
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Bidentate chiral phosphine ligands have received increasing
attention because of their important role in the development
of asymmetric catalytic applications of transition metal complexes.
1 The substituents at the two phosphorus atoms play an
important role in the steric and electronic properties of the
ligands.2 Their nature determines the relative donor/acceptor
ability of the phosphines.3 Dicarba-closo-dodecaborane(12) is
a particularly interesting substituent or backbone because
of its electron-withdrawing character,electron-delocalizing
ability,and large size.4
Derivatives of bidentate bis-phosphinodicarba-closododecaboranes(
12) can form stable complexes with platinum(
II) and palladium(II) because of their ability to form
five-membered chelate rings.5 Lately,severalmetal complexes
with five-membered chelate rings were reported to exhibit
high catalytic activity.6
attention because of their important role in the development
of asymmetric catalytic applications of transition metal complexes.
1 The substituents at the two phosphorus atoms play an
important role in the steric and electronic properties of the
ligands.2 Their nature determines the relative donor/acceptor
ability of the phosphines.3 Dicarba-closo-dodecaborane(12) is
a particularly interesting substituent or backbone because
of its electron-withdrawing character,electron-delocalizing
ability,and large size.4
Derivatives of bidentate bis-phosphinodicarba-closododecaboranes(
12) can form stable complexes with platinum(
II) and palladium(II) because of their ability to form
five-membered chelate rings.5 Lately,severalmetal complexes
with five-membered chelate rings were reported to exhibit
high catalytic activity.6
双齿手性膦配体日益受到
注意,因为他们在发展的重要作用
对过渡金属配合物的不对称催化应用.
1在两个磷原子取代发挥
重要作用的空间位阻和电子特性
ligands.2他们的性质决定的亲属供/受体
在phosphines.3 Dicarba能力硼- dodecaborane（12）
一个特别有趣的取代或骨干力量,因为
delocalizing其吸电子性质,电子
有能力,有大size.4
二是齿衍生物phosphinodicarba - closododecaboranes（
12）可与铂稳定的复合物（
II）和钯,因为它们有能力形成（二）
五员螯合rings.5最近,severalmetal物
与五元环螯合物据报告,展览
高催化activity.6
注意,因为他们在发展的重要作用
对过渡金属配合物的不对称催化应用.
1在两个磷原子取代发挥
重要作用的空间位阻和电子特性
ligands.2他们的性质决定的亲属供/受体
在phosphines.3 Dicarba能力硼- dodecaborane（12）
一个特别有趣的取代或骨干力量,因为
delocalizing其吸电子性质,电子
有能力,有大size.4
二是齿衍生物phosphinodicarba - closododecaboranes（
12）可与铂稳定的复合物（
II）和钯,因为它们有能力形成（二）
五员螯合rings.5最近,severalmetal物
与五元环螯合物据报告,展览
高催化activity.6
Bidentate chiral phosphine ligands have received increasing
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