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定语从句是he或those后面的定从只能用who不能用that吗

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定语从句
是he或those后面的定从只能用who不能用that吗
定语从句是he或those后面的定从只能用who不能用that吗
要看句子里具体想强调的是哪部分了.例句:
Case I:
He who makes no mistakes makes nothing.不犯错将一事无成.
Those people who shouted at police are not criminals.那些向警察大叫的人不是罪犯.
Case II:
He wants to live alone is not the big deal that aproves he's becoming mature.他想单独住并没什么大不了,只是证明他成熟了.
Those tools are not helpful for my job that makes me crasy.那些工具根本不能对另我发狂的工作有所帮助.